Rehydroxylation dating

Contact Author Excavation site at Gran Dolina in Spain In times past, things that appeared old were simply considered old, maybe as old as Atlantis, the biblical flood or the earth itself. But nobody knew for sure how old. Then in the early twentieth century scientists began using absolute dating techniques, perhaps the most prominent of which is carbon It would be hard to imagine modern archaeology without this elegant and precise timing method. Now with carbon and other modern dating techniques we have a very good idea how old things are. The following is a list of dating techniques used in archaeology and other sciences. It is more or less in the order of discovery of each procedure. Stratigraphy Stratigraphy is the most basic and intuitive dating technique and is therefore also the oldest of the relative dating techniques. Based on the law of Superposition, stratigraphy states that lower layers should be older than layers closer to the surface, and in the world of archaeology this is generally the case, unless some natural or manmade event has literally mixed up the layers in some fashion.

Denise Regan

The reconstruction of the chronology of historical buildings is a tricky issue, as usually there are not historical documents that allow the assessment of construction phases, and some materials are hardly reliable for the use of dating techniques e. However, in the last two decades, important advances on the use of absolute dating methods on building materials have increased the possibilities of reconstructing building chronologies, although some advances are still scarcely known among archaeologists and architects.

Recent studies performed on several kinds of mortars, fired bricks, mud-bricks, and even stone surfaces have shown that it is possible to date them. Both radiocarbon and luminescence dating have been the most frequently used techniques but others such as archaeomagnetism can also be used in some cases. This paper intends to give an overview of the recent achievements on the use of absolute dating techniques for building materials.

A study of the mass-gain of ancient pottery in relation to archeological ages using thermal analysis In firing at temperatures no higher than °C the fired clay is defined as meta-clay (Shoval et al., a).

Gallery themes and content. Ancient Worlds , Ancient Worlds Blog , archaeology collection , dating ceramics , dating techniques in archaeology , manchester museum , manchester wordsquare , rehydroxylation , RHX , science and archaeology , word square. Sarah-Jane kindly agreed to contribute an explanation of the technique and how it works to the Ancient Worlds Blog. She and Dr Moira Wilson plan to test the technique using pieces of pottery found in the same pit as the Manchester wordsquare.

The predictable way in which fired clay material absorbs environmental moisture via a process called rehydroxylation RHX provides, for the first time, a method of directly dating archaeological ceramics. In many respects the concept of RHX dating is simple and can potentially provide a date of manufacture for archaeological ceramics. This would be very useful for archaeologists studying all periods of our past. This research is led by Moira Wilson, who discovered that rehydroxylation proceeds at a predictable rate and co-invented the RHX dating technique.

This is how it works: The long-term moisture expansion of bricks has been known to structural engineers for some time, as it is the cause of cracking in brick masonry due to expansive stresses.

Utah Pottery Project Archaeology Blog:

Though it has only been established on bricks and tiles of up to 2, years of age, research is continuing to determine whether RHX can be accurately used on any fired-clay material, for example earthenware of up to 10, years of age. In fact this brick had been dehydroxylated by the intense heat of incendiary bombing and fires during World War II. Yet most archaeological material contains components which causes either addition mass gain or additional mass loss during the RHX measurement process.

It requires ‘calibration’ by radiocarbon dating of the surrounding site. If combined with statistical procedures (pottery seriation) then dating precision in the order of decades is achievable.

I know many people are very excited about RHX dating and also very skeptical. I was very excited about the proposed technique when it was published in This technique proposes to use the clock-like, nano-scale process by which water molecules bond with clay mineral crystals. After that, carefully tracking the mass of the sample as it quickly starts to reabsorb water from the air allows you to generate an equation that models the time past, the water mass gained, and the rate at which this occurs.

So long as you can match the temperature in the room to the average lifetime temperature of the object, a bit of math lets the lab technician calculate how long it took for the sample to reach the weight at which it was discovered by archaeologists. All my posts about RHX dating are all here. In , we applied for an NSF grant to study this process and see if we could replicate the findings of the UK researchers that had proposed it.

We did win that grant, but we did some background work and tried to replicate their study. We published our results in With that publication under our belt, we reapplied to NSF for more funding to upgrade our lab equipment to match the quality of that being used by the UK team. At first, we were rejected , but then the NSF found a bit of money that allowed us to improve our instruments. This microbalance allows us to measure 0.

It’s was a lesser piece of equipment than we’d hoped to purchase, but it has permitted us to take our experiments to the next level of research quality. In November-December , We tested the station to determine the stability of humidity and temperature within the box as well as the stability of microbalance while it is reading in the box chamber environment.

RHX Rehydroxylation Dating Technique

The reaction is accompanied by an expansion, and also by the small but measurable mass gain that provides the basis of the RHX dating method. The rate of the RHX reaction increases with increasing temperature. Here we describe comprehensively the effects of temperature on the RHX process in relation to the dating methodology.

Like thermoluminescence, rehydroxylation (RHX) is used to date ceramics. According to scientific observation, once a ceramic is fired it immediately begins to absorb moisture from the atmosphere at a measurable rate – the fourth root of the time elapsed since firing, actually.

The RHX method depends on the validity of this law for describing long-term RHX weight gain on archaeological timescales. There is now strong support for power-law behaviour from analyses of long-term moisture expansion data in brick ceramic, some of which now extends over more than 60 y. The amount of water lost in the dehydration process and thus the amount of water gained since the ceramic was created is measured with a microbalance. Once that RHX rate is determined, it is possible to calculate exactly how long ago it was removed from the kiln.

Sufficient water is available in virtually all terrestrial environments. Neither systematic nor transient changes in humidity have an effect on long-term rehydroxylation kinetics, though they do affect instantaneous gravimetric measurements or introduce systematic error i. Thus, when calculating dates, scientists must be able to estimate the temperature history of the sample. The method of calculation is based on temperature data for the location, with adjustments for burial depth and long-term temperature variation from historical records.

Any event involving exposure to extreme heat may reset the “clock” by dehydroxylating the specimen, as though it were just out of the kiln. For example, a medieval brick examined by Wilson and collaborators [1] produced a dating result of 66 years. In fact this brick had been dehydroxylated by the intense heat of incendiary bombing and fires during World War II.

Timothy James Scarlett

Thursday, January 13, How to Date Pottery by Rehydroxylation The method of rehydroxylation dating was first announced nearly two years ago, but this story in the Michigan Tech News may make the process more understandable than the earlier technical articles. And it reveals some of the complexities. If you are an archaeologist, determining when a pot was made is not just a matter of checking the bottom for a time stamp.

Dating clay-based materials like ceramics recovered from archeological sites can be time consuming, not to mention complex and expensive. Patrick Bowen, a senior majoring in materials science and engineering, is refining a new way of dating ceramic artifacts that could one day shave thousands of dollars off the cost of doing archaeological research.

Called rehydroxylation dating, the technique was recently developed by researchers at the University of Manchester and the University of Edinburgh.

We show that the rehydroxylation (RHX) method can be used to date archaeological pottery, and give the first RHX dates for three disparate items of excavated material. These are in agreement with independently assigned dates.

Request Quote Sponsored by Quantachrome Instruments Jun 28 The rehydroxylation RHX dating technique is a completely unexpected result of a study of the reversibility of moisture expansion in fired clay brick. The RHX process is the chemical absorption of atmospheric water by fired clay ceramic that proceeds by very slow nanoscale solid-state transport or single file diffusion into the clay body.

The rehydroxylation process is a chemical reaction and is based on temperature. Aquadyne DVS Gravimetric Water Sorption Analyzer RHX Dating Methodology The RHX dating methodology is quite straightforward, however producing data of enough quality to offer an age estimate for a fired ceramic piece is more difficult as a super-slow rate mass gain due to RHX needs to be measured which is an increase of 6 mg over 3 days.

One must be able to measure very small mass changes under constant environmental conditions of relative humidity and temperature a task that can be easily done by the Aquadyne Dynamic Water Sorption Analyzer as shown in Figure 2. This graph shows raw experimental data for m2 to demonstrate the level of precision that it is necessary for RHX dating. This can only be achieved by maintaining constant conditions of temperature and relative humidity.

At these conditions the sample is made to come to equilibrium.

Professor Christopher Hall

A methodological study of a simplified rehydroxylation dating procedure Rehydroxylation is a developing method of dating fired materials that was introduced to fired brick in and archaeological pottery in This technique is based upon dating the Stage II kinetics of the rehydroxylation process using The original rehydroxylation method utilised very expensive equipment so this experiment proposes a different measurement protocol that most university laboratories can implement easily.

Some scholars have noticed flaws in this original formula and therefore this experiment will test an amalgamation of their proposed alternative models.

A. Hamza, S. Derogar and C Ince ‘The effects of silica fume and hydrated lime on the strength development and durability characteristics of concrete under hot water curing condition’ Proceedings of the Advances in Sustainable Construction Materials & Civil Engineering Systems ASCMCES, , Sharjah, United Arab Emirates, April ,

List of publications Shabbar, R. Archaeometry, 57 2 , Rehydroxylation of fired-clay ceramics: Factors affecting early-stage mass gain in dating experiments. Archaeometry, 56 4 , Dehydroxylation and rehydroxylation mechanisms in fired clay ceramic: Journal of the American Ceramic Society, 95 1 , The effect of dewatering on strength and setting time of hydraulic mortar. The influence of pozzolanic additions on the water retentivity of freshly-mixed hydraulic lime mortars. The application of electrical resistance measurements to water transport in lime-masonry systems.

Materials Science and Processing, 3 ,


The ability to predict expansion in structural masonry has come to be used to date archaeological ceramics via RHX dating. This method has significant implications for future conservation practice and will inform future heritage policy making. Until recently there has not been a general method which can precisely date archaeological ceramics.

Heritage professionals would benefit from an independent method of precisely determining the age of ancient and historic fired-clay materials. This method has been successfully applied to a range of structural ceramics.

fired bricks and pottery using a method called rehydroxylation (RHX) dating. It is based on a proposed empirical law [4] that describes the chemical kinetics of two related phenomena in Figure 1: Schematic of RHX dating of archaeological fired-clay objects (redrawn from [31]).

Heat Capacity Porosity of Bioceramics For bioceramics, especially implantable devices, porosity is a critical material characteristic. Many times bioceramics are being used to mimic the human bone which is a highly porous, but yet incredibly strong material. The desired physical characteristics such as cell adhesion, bone ingrowth, and vascularization will be heavily influenced by the porosity of the materials. Much research has been conducted not only looking at total porosity but looking at the ideal pore structure for promotion of cell, tissue, and muscle growth and adhesion.

Mercury porosimetry is an ideal technology for the measurement of 3 dimensional materials and is sensitive to the arrangement of pores. Quantachrome Instruments has a team of scientists with deep backgrounds in how the density, porosity measurement of ceramics can influence these performance characteristics. Matthias Thommes has regularly presented at the American Ceramic Society and published the following research articles specific to ceramics: Surface Area of nanomaterials Nanomaterials are ultrafine particles, less than nanometers in size.

Chronological dating

These are in agreement with independently assigned dates. We define precisely the mass components of the ceramic material before, during and after dehydroxylation. These include the masses of three types of water present in the sample: We describe the main steps of the RHX dating process: We propose a statistical criterion for isolating the RHX component of the measured mass gain data after reheating and demonstrate how to calculate the RHX age.

Utah Pottery Project Archaeology Blog Monday, October 1, RHX Dating Update. My collaborators and I mailed out some reports today about Fired Clay Ceramic Rehydroxylation Dating! The Utah Pottery Project: Historical and Industrial Archaeology of a Pioneer Industry.

Review History Abstract Accurate and precise dating methods are of central importance to archaeology, palaeontology and earth science. This paper investigates the expected precision and age range of rehydroxylation dating, a recently proposed technique for fired clays. An expression for combined measurement uncertainty is presented, which takes into account all significant sources of experimental uncertainty.

Numerical simulations are performed for comparison. In this case, the most significant contribution to combined measurement uncertainty is from effective lifetime temperature. In addition, it is shown that precision should be acceptable for recently fired material less than 1 year. Mismatch of balance resolution to sample mass results in large variation in combined relative uncertainties, which vary by four orders of magnitude approx.

The age limits of the technique are set by the value of the rate constant and individual sample mineralogy. This theoretical framework should help future interlaboratory comparison as well as optimizing instrument design. Context There are several factors that determine the usefulness of an analytical dating method when applied to archaeological material. These may be the potential destruction of valuable material, cost or the length of time taken for analysis.

However, of primary importance is the precision that the method is likely to afford, as well as the age range over which it is expected to be appropriate. Thus, in order to determine whether a new technique has any practical usefulness, the theoretical error limits need to be established [ 1 ].

The Importance of Pottery

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